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Firstorderwizard's Posts

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PoliticsRe: Peter Obi And Datti Ahmed At Wedding Today( Photos) by Firstorderwizard(m): 2:03pm On May 27, 2023
Nigeria have no President elect yet.
Anything other than this is state capture
EducationRe: Nigerians Have The Right NOT To Recognize Tinubu As President- Lawyer by Firstorderwizard(m): 12:55pm On May 27, 2023
This state capture is temporary anyway.
Let Tunubu be warming that seat.
I particularly wanted the Friday SC judgement to favor him.
Don't want Buhari to stay beyond Sunday in Aso rock
PoliticsRe: Cultism Or Dirtiness? See What Obi's Black Cloth Turnin Into because Of Politics by Firstorderwizard(m): 3:06pm On May 23, 2023
Maize247:
Politics apart Obi needs urgent psychological examination. Obi that's always very neat now turning into something else. His dressing now looking unpresidential and this particular has probably not been changed in the last four days.

My advice, if Obi insists on wearing only black, at least, Obidents should be able to afford as many as possible.
Karemarealty288:
You Papa no reach to be Obi's gateman talk more of driver. Show us your Papa and I will give you 50k cash if your father has University degree....I challenge you.
I will contribute 50k to this challenge to make it 100k.
If OP can proof his father has any class of BSC degree.
Let him provide an escrow

Infact I will give him 20K from the 50K if He can proof his father has a polytechnic National Diploma or College of education NCE.
5K if He can proof his father made 5 credit level passes in one WAEC sitting

2K if his father made a B grade in primary school leaving certificate
PoliticsRe: Commissioning Of Dangote Refinery: Peter Obi Arrives Lagos by Firstorderwizard(m): 9:56pm On May 22, 2023
The last time I checked, Vladimir Putin's best suit colour is black. Its a well known fact that his best colour is black.
I used him as reference cos he is the most fearless man right now in the whole wide world. He represents power.

https://www.news.com.au/lifestyle/fashion/inside-vladimir-putins-expensive-designer-wardrobe/news-story/2195b9110c3850a87a07c726b5913a0d

BlackKafka:
Navy blue is the default colour for power suits.
PoliticsRe: Commissioning Of Dangote Refinery: Peter Obi Arrives Lagos by Firstorderwizard(m): 7:45pm On May 22, 2023
If OBI choose to putting on white color the same low intelligence black man will link it to ogboni or sth else.
The average American President, British prime Minister and French President puts on more black colours than other colours.
Why is black suit seen as more corporate compared to other colours ?
Don't argue what you don't know

BlackKafka:
By your logic funeral undertakers and the Nigeria Police should be in the Mensa club.
PoliticsRe: Commissioning Of Dangote Refinery: Peter Obi Arrives Lagos by Firstorderwizard(m): 1:38pm On May 22, 2023
I once worked with a female Senior French Engineer in Port Harcourt whose ward robe is only black clothes except her PPE.
Even her umbrella is black.
There are rare intelligent peeps that prefer black colors because it reflects no light.
Talking from experience


Sparrk007:
I love this man but his love for black clothes just dey fear me
PoliticsRe: Fact Check: Did Obi Request 7 Weeks From Tribunal To Produce Witnesses? by Firstorderwizard(m): 5:58am On May 22, 2023
We intelligent folks already know APC propaganda when we see one.
I didn't even bother to open the paid propaganda on front page.

Watch as the truth presented in this thread will take days to make front page or not even make front page
PoliticsRe: Deji Lambast Labour Party For Openly Cutting Deals With APC by Firstorderwizard(m): 7:13pm On May 18, 2023
This is national assembly business.
In Parliamentary system, two opposing parties with different ideologies can meet to reach a common ground in forming the next Parliamentary government.
So many dumb people in this country
PoliticsRe: Livy Uzoukwu: What Is INEC Hiding? Obi's Lead Counsel Asks (Video) by Firstorderwizard(m): 8:54pm On May 17, 2023
Mahmoud Yakubu is fighting for his protection.
He knows he will account for the #300 billion he misused if OBI becomes President
EducationRe: Waec 2023 Chemistry Practical Practice Questions by Firstorderwizard(m): 3:27pm On May 17, 2023
Just came across this and decided to correct something.
Al3+ and Zn2+ form white gelatinous precipitate with drops of NaOH that dissolve in excess sodium hydroxide, while Pb2+ forms white chalky precipitate with drops of NaOH that dissolves in excess NaOH too.
A good observer shouldn't be suspecting Pb2+ when the ppt formed is gelatinous.

I left secondary school a long time ago anyway


Oduok:
Chemistry practical has three questions.

Question 1 is quantitative analysis (titration). This year we expect titration between a strong acid and weak base. The base will be a salt with water of crystalization.

Question 2 is qualitative analysis. This year we expect analysis of an organic and inorganic compound.

Question 3 is always general chemistry theory question.

This is not expo. It is for practice purpose.

Feel free to leave your questions, comments and contributions.



Question 1
A is a solution containing 0.100 moldm-3 of hydrochloric acid. B is a solution containing 5.0 g per dm3 of hydrated sodium trioxocarbonate (iv), Na2CO3.xH2O.

(a)Put A into the burette and titrate it against 20.00 cm3 or 25.00 cm3 portion of B using methyl orange as indicator. Record the volume of your pipette. Tabulate your burette readings and calculate the average volume of A used.

Equation for the reaction:
Na2CO3.xH2O(aq) + 2HCl(aq) 2NaCl(aq) + CO2(g) + (x+1)H2O(l)
(b)From your results, calculate the:
(i)Concentration of B in moldm-3.
(ii)Molar mass of Na2CO3.xH2O.
(iii)Value of x in Na2CO3.xH2O.
[H = 1.0, C = 12.0, O = 16.0, Na = 23.0]

ANSWER TO QUESTION 1
1.(a) Volume of pipette used = 25.00 cm3.
Indicator used = Methyl orange
Burette Reading 1st Titre 2nd Titre 3rd Titre
Final volume of A (cm3) 8.80 17.50 26.30
Initial Volume of A (cm3) 0.00 8.80 17.50
Volume of A used (cm3) 8.80 8.70 8.80

Average volume of Acid used = (8.80 + 8.70 + 8.80) / 3
= 26.3/3 = 8.77cm3

(b) (i) Concentration of B in moldm-3:
(Ca x Va)/(Cb x Vb) = A/B
(0.10 x 8.77)/(Cb x 25.00) = 2/1
Cb = (0.10 x 8.77)/(25.00 x 2) = 0.877 / 50 = 0.0175 moldm-3.

(ii) Molar mass of Na2CO3.xH2O = mass conc. / molar conc.
= 5.0 / 0.0175 = 285.7 g/mol
(iii) Value of x in Na2CO3.xH2O:
285.7 = 106 + 18x
x = (285.7 - 106)/18 = 179.7 / 18 = 9.98 approximately 10

Question 2: Carry out the following exercises on specimen C and D. Record your observations and identify any gases evolved. State the conclusion you draw from the result of each test:

a.(i) Add about 5cm3 of distilled water to a portion of C in a test tube. Stir thoroughly and test with litmus.
(ii). Add about 2cm3 of Fehling’s solution to the resulting mixture from (a)(i) above and heat.
b.(i) Heat a portion of D strongly in a test tube.
(ii) Put the rest of D in a boiling tube and add about 10cm3 of distilled water. Shake the mixture.
(iii) Put about 2cm3 of the mixture from b(ii) in a test tube. Add aqueous NaOH in drops and then in excess.
(iv) Put about 2cm3 of the mixture from b(ii) in a test tube. Add aqueous ammonia in drops and then in excess.

ANSWERS FOR QUESTION 2
S/N TEST OBSERVATION INFERENCE
(a)(i) C + distilled water Soluble in distilled water C is a soluble compound
+ Litmus No effect on litmus C is a neutral compound
(ii) Solution of C + Fehling’s solution + Heat Brick-red precipitate C is a reducing sugar (glucose)
(b)(i) D + heat Yellow when hot and white when cold D is zinc oxide (ZnO)
(ii) D + water Does not dissolve in water D is an insoluble compound
(iii) Mixture from (b)(ii) + NaOH(aq) in drops and in excess White precipitate. Precipitate dissolves in excess Al3+, Zn2+, Pb2+ present
(iv) Mixture from (b)(ii) + NH3(aq) in drops and in excess White precipitate. Precipitate dissolves in excess Zn2+ Confirmed
PoliticsRe: The Mystery Of The Altered Results In Nigeria's Disputed 2023 Election - BBC by Firstorderwizard(m): 6:13am On May 16, 2023
Swearing in Tunubu will mark the end of democracy in this country.
RomanceRe: He Waited Until I Broke Up With My Boyfriend — Lady Narrates How She Met Husband by Firstorderwizard(m): 8:24pm On May 15, 2023
Flesh and blood did not reveal this to you undecided



oz4real83:
most women have an unusual kind of attraction for cars to the extent that they can easily fall in love with car owners irrespective of the car owner's personality, her former boyfriend can still win her back if he buys a car better than the one the girlfriend snatcher has cheesy grin
RomanceRe: Why Are Most Nigerian Girls Not Technically Savvy? by Firstorderwizard(m): 1:43pm On May 13, 2023
I can see this beautiful thread that tends to voice out gender imbalance in simple survival home skills in terms of technical know how has been hijacked by nairaland feminists.

Fortunately, we still have the few wife materials here who agreed with the op that it's true that some women are clueless in technology but the multiple body count, heartbroken and evening newspaper feminists will always display themselves at any little opportunity
CelebritiesRe: Davido Puts Up His Banana Island House For Rent by Firstorderwizard(m): 1:21pm On May 13, 2023
omoadeleye:
Lolz , stfu , quick to reply, retard to comprehend.

You can recognise poverty induced opinions but you are an illiterate to know the meaning of 150k dolls to 6m naira.

You be olodo
You think everyone is poor like you.
Go to property rental listings and see 500 million per annum houses. Is it not Nigerians that are paying for it ?
150k dolls is not even up to 100m.
Some people make 200m per week in this same country .
What is 150k dolls?
PoliticsRe: FG Ends Feeding Of Inmates In 2024 by Firstorderwizard(m): 11:36am On May 13, 2023
Just thinking of what Zamfara prisoners will be eating in 2024 grin
CelebritiesRe: Charles Inojie Escapes Death From Collapsed Water Tank (Video) by Firstorderwizard(m): 11:33am On May 13, 2023
You need to consider the location bro.
no space .
Quarter plot of land there is worth more than 2 plots of land in many cities in this country.
Every inch of the land is utilized

zicoraads:
Why would anyone build a water tank under a sitting spot or even close to it? We thank God for sparing him. However, his carelessness almost resulted to his death.
CelebritiesRe: Davido Puts Up His Banana Island House For Rent by Firstorderwizard(m): 11:22am On May 13, 2023
You are quoting an estate manager
Giving me 18m within a space of 3 years (6m per year )and I will buy land and build a decent house for you with fence and running water in a not too remote area in PH


Rubbiish:
Lolzzz are u sure u are in Nigeria?
Go ask how much for bag of cement & building materials
CelebritiesRe: Davido Puts Up His Banana Island House For Rent by Firstorderwizard(m): 10:52am On May 13, 2023
Someone that can afford 6m rent can equally afford to buy land and build a decent house


Rubbiish:
Your analogy is wrong
6m can't get u any decent land talk more of building. You can't be comparing that to over a 110m naira.
CelebritiesRe: Davido Puts Up His Banana Island House For Rent by Firstorderwizard(m): 10:48am On May 13, 2023
If only you understand what it means to build mansion in a neighborhood or street of majority poor people.
Do you know some rich people have abandoned houses they built in low class income neighbourhoods and rushed back to GRA's and rich neighborhoods even if it means renting properties?
I am not rich but comfortable but my job involves daily contact with the rich class of people.
If you get in their shoes you will understand .



wildikeman:
That's pounds foolish to me....una and pepper dem lifestyle no dey do una for this yeye country
RomanceRe: Why Are Most Nigerian Girls Not Technically Savvy? by Firstorderwizard(m): 9:48pm On May 12, 2023
They should get there acts right then.
Your gender people can't be forming feminists and at the same time delegating skilled roles to men.
Like someone said up there.
45 years old aunty begging 15 years old boy to fix bulb for her in this age and time




lilyheaven:
It’s not their fault, it’s because someone is getting it done for them.
Many times it’s upbringing too.
Don’t touch it , don’t it.
They will grow up with fears.
My momma no send us , while we were growing up, we took care of our responsibilities, like bathing eating, wearing our clothes, etc
If you like don’t eat, nobody cares, na stream we dey go bath sef .
I started climbing trees when I was small, even coconut trees.😃
Come to plumbing work, I fix .
Small small electrical work at home, I fix them.
meanwhile , my husband who is a man that should be doing all these things , will be doing sme-sme-.

I have visited a woman once, they had power supply ooo... madam switch on TV , she said she doesn’t know how to do it, she’s waiting for her husband 🙄
I just weak for her.
RomanceRe: Why Are Most Nigerian Girls Not Technically Savvy? by Firstorderwizard(m): 8:13pm On May 12, 2023
I wanted to dismiss this thread as another nairaland redpillers stunt but sadly it's true.
Our girls are very poor in technology.
Simple home machines hard for them to manage.
Most of them can't operate ordinary water pumping machine at home
PoliticsRe: Big Story: Peter Obi’s LP Won 16 States, Not 12. IREV Results Show. by Firstorderwizard(m): 11:48am On May 12, 2023
Benue, Rivers, Taraba and Bayelsa
Irev is still open




Raheeqilmaktoom:
Not even at the very least the names of those states won by Mr. Obi.
EducationRe: Anambra Students Create Smart Walking Sticks For The Blind(photo) by Firstorderwizard(m): 9:20pm On May 10, 2023
It's not by shouting Igbo this and that with MTN borrowed data..
Travel out of your village and take a tour.
Go and verify Peter OBI's investment in Anambra state
PoliticsRe: Another Perspective On Whether 25% Is Mandatory In The Fct Or Not by Firstorderwizard(m): 7:27pm On May 10, 2023
The court will decide


Globad:
Tinubu will win this
TravelRe: Disadvantages Of Living Abroad Or Obodo Oyinbo by Firstorderwizard(m): 5:14pm On May 10, 2023
Tell us the advantages let's weigh it side by side
PoliticsRe: Another Perspective On Whether 25% Is Mandatory In The Fct Or Not by Firstorderwizard(m): 5:12pm On May 10, 2023
No need to quote me. Let's wait for the court proceedings.
I pray the court approves live coverage


garfield1:
Obi and atiku cases are already dead going by the recent judgment sir which upheld bvas and irev
PoliticsRe: Another Perspective On Whether 25% Is Mandatory In The Fct Or Not by Firstorderwizard(m): 3:58pm On May 10, 2023
Tunubu has a very bad case which the recent Supreme court judgement has made worst ( those that have legal eyes will understand)
His only saving grace is technicalities unfortunately, the case is too water tight to be dismissed by technicalities
PoliticsRe: Photo: Osinbajo Commissions Transcorp Afam III Fast Power 240MW Turbines by Firstorderwizard(m): 9:13pm On May 09, 2023
Aba/Obigbo axis is fast becoming an electric power hub.
Aba under Incoming Gov. Otti should give us the first 24 hrs light for one full year in a Nigerian city to set a record for other Nigerian cities
EducationRe: Why Anambra Has The Best School Completion Rate Across Basic & Secondary Level N by Firstorderwizard(m): 11:26am On May 07, 2023
I don't believe in witches before but I'm beginning to change my mind that it exists in black Africa.
This beautiful thread is supposed to generate good will comments considering education is one of our greatest set back but no. Some dark hearted mofos are busy churning out hateful comments .
Dunno why I'm sharing a country with this set of people
Foreign AffairsRe: Coronation Of King Charles III In Pictures by Firstorderwizard(m): 6:10pm On May 06, 2023
Sometimes before you take certain decisions in life consider your future generation.
Prince Harry future generation will never forgive him for wiping them off the royal blood
PoliticsRe: Adesoji Adesida: OPC Member Pushes Ondo Prince To Death During Funeral In Akure by Firstorderwizard(m): 10:45am On May 05, 2023
In conclusion, the OPC man will be in jail, His girlfriend will be enjoying and riding a brand new gbola while the Ondo Prince will have a new home in heaven (most likely hell)
*****THE END*****

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